Abstract: The progress of composite materials applied to ground radomes was comprehensively reviewed. The requests of materials of high performance radomes needed was summed up briefly. It was also related to the comprehensive analysis of the advantages, disadvantages and modification methods of several kinds of reinforced fibers, matrix resin, and core materials. At the same time the developing trends of materials applied to ground radome were also described. The progress of composite materials applied to ground radomes was comprehensively reviewed. The requests of materials of high performance radomes needed was summed up briefly.