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    H2S/CO2分压比对N80钢油管均匀腐蚀的影响

    Effect of H2S/CO2 partial pressure ratio on uniform corrosion of N80 steel tubing

    • 摘要: 采用扫描电镜及能谱分析、X射线衍射分析等方法,对某油田群注水井N80钢油管在H2S和CO2两种腐蚀性气体共存时的腐蚀机制进行研究,并研究不同温度、气体质量分数、H2S/CO2分压比等因素对油管腐蚀行为的影响。结果表明:油管表面的腐蚀产物主要为FeS;H2S和CO2分压比是影响均匀腐蚀速率的主要原因;在H2S质量分数固定不变时,无论CO2质量分数增加还是减小,均匀腐蚀速率不会发生较大变化;在同一温度条件下,均匀腐蚀速率主要受H2S分压控制。

       

      Abstract: The corrosion mechanism of N80 steel tubing in an oilfield group of water injection wells in the coexistence of H2S and CO2 corrosive gases was studied by means of scanning electron microscopy and energy spectrum analysis, and X-ray diffraction analysis. The effects of different temperature, gas mass fraction and H2S/CO2 partial pressure ratio on the corrosion behavior of tubing were studied. The results show that the corrosion products on the surface of the tubing were mainly FeS. The partial pressure ratio of H2S and CO2 was the main reason affecting the uniform corrosion rate. When the mass fraction of H2S was fixed, the uniform corrosion rate would not change greatly whether the mass fraction of CO2 increased or decreased. Under the same temperature condition, the uniform corrosion rate was mainly controlled by H2S partial pressure.

       

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