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    船舶冷却系统铜镍合金管腐蚀穿孔原因

    Causes of corrosion perforation of copper-nickel alloy tube in ship cooling system

    • 摘要: 采用体视显微镜、金相显微镜、电子探针等分析测试方法对腐蚀穿孔失效的BFe10-1.6-1铜镍合金管进行失效分析。结果表明:失效管的内壁存在不同程度的划痕,且腐蚀坑内壁显微组织呈现“波纹”状,符合海水冲刷腐蚀的特征;腐蚀区的显微组织呈现“冰糖块”状,符合晶间腐蚀的特征;腐蚀坑内的泥沙沉积致使管道发生点蚀。结合船用铜镍合金管的使用工况,确认该失效管腐蚀穿孔失效的主要原因是海水冲刷腐蚀、晶间腐蚀及点蚀。

       

      Abstract: The failure analysis of BFe10-1.6-1 copper-nickel alloy tube with corrosion perforation failure was carried out by stereomicroscope, metallographic microscope and electronic probe. The results show that there were different degrees of scratches on the inner wall of the failure tube, and the microstructure of the inner wall of the corrosion pit was ‘ripple’, which was consistent with the characteristics of seawater erosion and corrosion. The microstructure of the corrosion zone was ‘ice sugar block’, which was consistent with the characteristics of intergranular corrosion. Sediment deposition in corrosion pits caused pitting of pipelines. Combined with the working conditions of marine copper-nickel alloy tube, it was confirmed that the main causes of corrosion perforation failure of the failure tube were seawater erosion corrosion, intergranular corrosion and pitting corrosion.

       

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