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    超音速火焰喷涂WC-CoCr和WC-Ni涂层在NaCl溶液中的腐蚀行为

    Corrosion Behavior of High Velocity Oxygen Fuel Sprayed WC-CoCr and WC-Ni Coatings in NaCl Solution

    • 摘要: 利用金相显微镜、扫描电镜和X射线衍射仪等,分析了超音速火焰喷涂WC-CoCr和WC-Ni金属陶瓷涂层的物相组成和显微结构。通过电化学工作站测试了涂层在3.5%(质量分数)NaCl溶液中的动电位极化曲线和奈奎斯特阻抗谱,并与镀铬层进行了对比。结果表明:该涂层由WC硬质相和金属黏结相组成,组织均匀致密无分层,孔隙率低于1.5%;在NaCl溶液中的耐腐蚀性能从高到低依次为WC-CoCr涂层、WC-Ni涂层、镀铬层;超音速喷涂涂层组织致密,Cl-难以穿透涂层,因此其耐腐蚀性能较高;添加少量的铬可以促使CoCr合金黏结相表面形成钝态膜,因而WC-CoCr涂层的耐腐蚀性能优于WC-Ni涂层的。

       

      Abstract: The phase composition and microstructure of high velocity oxygen fuel (HVOF) sprayed WC-CoCr and WC-Ni cermet coatings were analyzed by metallographic microscope, scanning electron microscope, X-ray diffractometer and so on. The potentiodynamic polarization curves and the Nyquist impedance spectra of the coatings in 3.5% (mass fraction) NaCl solution were measured by electrochemical workstation and compared with those of the chromium layer. The results show that: the coatings consisted of WC hard phase and metal binder phase, with a homogeneous and dense microstructure and porosity less than 1.5%; in NaCl solution, the corrosion resistance from high to low was that of WC-CoCr coating, WC-Ni coating, chromium layer; the structure of the HVOF coatings was dense, which prevented the coatings from Cl-, thus the corrosion resistance of the coatings was better; the addition of a little chrome promoted the formation of a passive film on the surface of CoCr binder phase, thus the corrosion resistance of WC-CoCr coating was better than that of WC-Ni coating.

       

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